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Hyperfine structure of alkali-metal diatomic molecules.

Aldegunde, Jesus and Hutson, Jeremy M. (2017) 'Hyperfine structure of alkali-metal diatomic molecules.', Physical review A., 96 (4). 042506.

Abstract

We present calculations of the hyperfine coupling constants for all the heteronuclear alkali-metal diatomic molecules at the equilibrium geometry of the electronic ground state. These constants are important in developing methods to control ultracold polar molecules. The results are based on electronic structure calculations using density-functional theory, and are in good agreement with experiment for the limited set of molecules for which experiments are so far available.

Item Type:Article
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Status:Peer-reviewed
Publisher Web site:https://doi.org/10.1103/PhysRevA.96.042506
Publisher statement:Reprinted with permission from the American Physical Society: Aldegunde, Jesus & Hutson, Jeremy M. (2017). Hyperfine structure of alkali-metal diatomic molecules. Physical Review A 96(4): 042506 © 2017 by the American Physical Society. Readers may view, browse, and/or download material for temporary copying purposes only, provided these uses are for noncommercial personal purposes. Except as provided by law, this material may not be further reproduced, distributed, transmitted, modified, adapted, performed, displayed, published, or sold in whole or part, without prior written permission from the American Physical Society.
Date accepted:18 August 2017
Date deposited:07 November 2017
Date of first online publication:27 October 2017
Date first made open access:07 November 2017

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