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Electrochemistry and spectroelectrochemistry of polymers based on D-A-D and D-D-D bis( N -carbazolyl) monomers, effect of the donor/acceptor core on their properties

Pander, P.; Swist, A.; Zassowski, P.; Soloducho, J.; Lapkowski, M.; Data, P.

Electrochemistry and spectroelectrochemistry of polymers based on D-A-D and D-D-D bis( N -carbazolyl) monomers, effect of the donor/acceptor core on their properties Thumbnail


Authors

A. Swist

P. Zassowski

J. Soloducho

M. Lapkowski

P. Data



Abstract

In this work we present electropolymerization of monomers of an unusual type using N-linked carbazole units to limit their conjugation. The polymers thus obtained have limited conjugation through the backbone. Using donor-acceptor-donor (D-A-D) and donor-donor-donor (D-D-D) monomers we evaluate the effects of the presence (or absence) of charge transfer states on synthesized electropolymers. The use of a D-A-D monomer resulted in obtaining an ambipolar polymer with quasi-reversible reduction.

Citation

Pander, P., Swist, A., Zassowski, P., Soloducho, J., Lapkowski, M., & Data, P. (2017). Electrochemistry and spectroelectrochemistry of polymers based on D-A-D and D-D-D bis( N -carbazolyl) monomers, effect of the donor/acceptor core on their properties. Electrochimica Acta, 257, 192-202. https://doi.org/10.1016/j.electacta.2017.10.023

Journal Article Type Article
Acceptance Date Oct 3, 2017
Online Publication Date Oct 7, 2017
Publication Date Oct 7, 2017
Deposit Date Oct 19, 2017
Publicly Available Date Mar 28, 2024
Journal Electrochimica Acta
Print ISSN 0013-4686
Publisher Elsevier
Peer Reviewed Peer Reviewed
Volume 257
Pages 192-202
DOI https://doi.org/10.1016/j.electacta.2017.10.023

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