Walter, Edward R. H. and Williams, J. A. Gareth and Parker, David (2017) 'Solvent polarity and oxygen sensitivity, rather than viscosity, determine lifetimes of biaryl-sensitised terbium luminescence.', Chemical communications., 53 (100). pp. 13344-13347.
In a macrocyclic terbium complex incorporating a biaryl sensitiser, the observed variation of emission lifetime is shown to be determined by the solubility of oxygen in the solvent system and the relative energy of the chromophore excited state, rather than any dependence on solvent viscosity.
|Full text:||(AM) Accepted Manuscript|
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|Publisher Web site:||https://doi.org/10.1039/C7CC08361K|
|Date accepted:||24 November 2017|
|Date deposited:||01 December 2017|
|Date of first online publication:||30 November 2017|
|Date first made open access:||24 November 2018|
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