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Solvent polarity and oxygen sensitivity, rather than viscosity, determine lifetimes of biaryl-sensitised terbium luminescence.

Walter, Edward R. H. and Williams, J. A. Gareth and Parker, David (2017) 'Solvent polarity and oxygen sensitivity, rather than viscosity, determine lifetimes of biaryl-sensitised terbium luminescence.', Chemical communications., 53 (100). pp. 13344-13347.

Abstract

In a macrocyclic terbium complex incorporating a biaryl sensitiser, the observed variation of emission lifetime is shown to be determined by the solubility of oxygen in the solvent system and the relative energy of the chromophore excited state, rather than any dependence on solvent viscosity.

Item Type:Article
Full text:(AM) Accepted Manuscript
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Status:Peer-reviewed
Publisher Web site:https://doi.org/10.1039/C7CC08361K
Date accepted:24 November 2017
Date deposited:01 December 2017
Date of first online publication:30 November 2017
Date first made open access:24 November 2018

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