Dynamic behaviour in nicotinate-bridged binuclear ruthenium(IV) complexes

Steed, Jonathan W.; Tocher, Derek A.

doi:10.1016/j.poly.2018.03.025

Dynamic behaviour in nicotinate-bridged binuclear ruthenium(IV) complexes

Steed, Jonathan W.; Tocher, Derek A.

Authors

Professor Jonathan Steed jon.steed@durham.ac.uk
Professor

Derek A. Tocher

Abstract

The isonicotinic acid adduct [Ru(η3:η3-C10H16)Cl2(p-NC5H4CO2H)] 1 and nicotinate and isonicotinate bridged binuclear complexes [Ru2(η3:η3-C10H16)2Cl3(μ-κN,O,O′-NC5H4CO2)] 2 and 3 are reported. Complexes 2 and 3 exist as mixtures of diastereoisomers and are dynamic in water saturated chloroform solution with complexes involving bidentate chelating carboxylate ligands in equilibrium with unidente carboxylate aquo complexes [Ru2(η3:η3-C10H16)2Cl3(OH2)(μ-κN,O-NC5H4CO2)].

Citation

Steed, J. W., & Tocher, D. A. (2018). Dynamic behaviour in nicotinate-bridged binuclear ruthenium(IV) complexes. Polyhedron, 147, 152-155. https://doi.org/10.1016/j.poly.2018.03.025

Journal Article Type	Article
Acceptance Date	Mar 25, 2018
Online Publication Date	Apr 3, 2018
Publication Date	Jun 1, 2018
Deposit Date	Jun 8, 2018
Publicly Available Date	Apr 3, 2019
Journal	Polyhedron
Print ISSN	0277-5387
Publisher	Elsevier
Peer Reviewed	Peer Reviewed
Volume	147
Pages	152-155
DOI	https://doi.org/10.1016/j.poly.2018.03.025

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http://creativecommons.org/licenses/by-nc-nd/4.0/

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© 2018 This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/