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Dynamic behaviour in nicotinate-bridged binuclear ruthenium(IV) complexes.

Steed, Jonathan W. and Tocher, Derek A. (2018) 'Dynamic behaviour in nicotinate-bridged binuclear ruthenium(IV) complexes.', Polyhedron., 147 . pp. 152-155.

Abstract

The isonicotinic acid adduct [Ru(η3:η3-C10H16)Cl2(p-NC5H4CO2H)] 1 and nicotinate and isonicotinate bridged binuclear complexes [Ru2(η3:η3-C10H16)2Cl3(μ-κN,O,O′-NC5H4CO2)] 2 and 3 are reported. Complexes 2 and 3 exist as mixtures of diastereoisomers and are dynamic in water saturated chloroform solution with complexes involving bidentate chelating carboxylate ligands in equilibrium with unidente carboxylate aquo complexes [Ru2(η3:η3-C10H16)2Cl3(OH2)(μ-κN,O-NC5H4CO2)].

Item Type:Article
Full text:(AM) Accepted Manuscript
Available under License - Creative Commons Attribution Non-commercial No Derivatives.
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Status:Peer-reviewed
Publisher Web site:https://doi.org/10.1016/j.poly.2018.03.025
Publisher statement:© 2018 This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
Date accepted:25 March 2018
Date deposited:08 June 2018
Date of first online publication:03 April 2018
Date first made open access:03 April 2019

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