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Quantum magnetism in molecular spin ladders probed with muon-spin spectroscopy.

Lancaster, T. and Xiao, F. and Huddart, B. M. and Williams, R. C. and Pratt, F. L. and Blundell, S. J. and Clark, S. J. and Scheuermann, R. and Goko, T. and Ward, S.C. and Manson, J. L. and Rüegg, Ch. and Krämer, K. W. (2018) 'Quantum magnetism in molecular spin ladders probed with muon-spin spectroscopy.', New journal of physics., 20 (10). p. 103002.


We present the results of muon-spin spectroscopy (μ +SR) measurements on the molecular spin ladder system (Hpip)2CuBr4(1−x)Cl4x , [Hpip = (C5H12N)]. Using transverse field μ +SR we are able to identify characteristic behaviour in each of the regions of the phase diagram of the x = 0 strong-rung spin ladder system (Hpip)2CuBr4. Comparison of our results to those of the dimer-based molecular magnet Cu(pyz)(gly)(ClO4) shows several common features. We locate the crossovers in partially disordered (Hpip)2CuBr4(1−x)Cl4x (x = 0.05), where a region of behaviour intermediate between quantum disordered and Luttinger liquid-like is identified. Our interpretation of the results incorporates an analysis of the probable muon stopping states in (Hpip)2CuBr4 based on density functional calculations and suggests how the muon plus its local distortion can lead to a local probe unit with good sensitivity to the magnetic state. Using longitudinal field μ +SR we compare the dynamic response of the x = 1 strong-rung material (Hpip)2CuCl4 to that of the strong-leg material (C7H10N)2CuBr4 (known as DIMPY) and demonstrate that our results are in agreement with predictions based on interacting fermionic quasiparticle excitations in these materials.

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Publisher statement:Original content from this work may be used under the terms of the Creative Commons Attribution 3.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.
Date accepted:03 September 2018
Date deposited:10 October 2018
Date of first online publication:03 October 2018
Date first made open access:No date available

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