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Terrestrial sources as the primary delivery mechanism of mercury to the oceans across the Toarcian Oceanic Anoxic Event (Early Jurassic).

Them, T.R. and Jagoe, C.H. and Caruthers, A.H. and Gill, B.C. and Grasby, S.E. and Gröcke, D.R. and Yin, R. and Owens, J.D. (2018) 'Terrestrial sources as the primary delivery mechanism of mercury to the oceans across the Toarcian Oceanic Anoxic Event (Early Jurassic).', Earth and planetary science letters., 507 . pp. 62-72.

Abstract

This study evaluates the utility of sedimentary mercury (Hg) contents as a proxy for fingerprinting ancient massive volcanism, which is often associated with biogeochemical perturbations. Herein we present new Hg geochemical data from anoxic marine basins across the Toarcian Oceanic Anoxic Event (T-OAE; ∼183 Ma) as a test of the complex Hg cycle. The T-OAE was likely initiated by the main eruptive phase of the Karoo–Ferrar large igneous province, which caused a subsequent cascade of environmental perturbations and resulting mass extinction. At present the leading interpretation of sedimentary Hg anomalies has been volcanogenic outgassing as the primary source. Our study and compilation results suggest, however, that Hg/TOC anomalies were restricted to shallow-water, and/or proximal environments, while deep-water, more distal depositional settings document no significant Hg-related anomalies. Furthermore, asynchronous stratigraphic deviations in Hg enrichments favor terrestrially sourced materials and local redox variability, rather than direct volcanogenic emissions, as a primary control mechanism. Additionally, Hg isotope signatures from our only study site documenting an Hg anomaly are also consistent with a terrestrial Hg origin during the T-OAE. Therefore, our results suggest that Hg anomalies in the geological record need to be re-evaluated as a “smoking gun” proxy that only infers volcanogenic inputs.

Item Type:Article
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Full text:Publisher-imposed embargo
(AM) Accepted Manuscript
Available under License - Creative Commons Attribution Non-commercial No Derivatives.
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Status:Peer-reviewed
Publisher Web site:https://doi.org/10.1016/j.epsl.2018.11.029
Publisher statement:© 2018 This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
Date accepted:19 November 2018
Date deposited:14 December 2018
Date of first online publication:06 December 2018
Date first made open access:06 November 2019

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