Yuan, Guanghui and Cao, Yingchang and Zan, Nianmin and Schulz, Hans-Martin and Gluyas, Jon and Hao, Fang and Jin, Qiang and Liu, Keyu and Wang, Yanzhong and Chen, Zhonghong and Jia, Zhenzhen (2019) 'Coupled mineral alteration and oil degradation in thermal oil-water-feldspar systems and implications for organic-inorganic interactions in hydrocarbon reservoirs.', Geochimica et cosmochimica acta., 248 . pp. 61-87.
Organic-inorganic interactions after oil charging are critical for determining the ongoing evolution of hydrocarbons and rock quality in water-wet siliciclastic reservoirs. It is the conceptual approach of this study to simulate and decipher these interactions by using quantitative analyses of the interrelated changes of minerals, water, hydrocarbons, gases, and organic acids in heated oil-water-rock systems. The experimental results show that organic-inorganic interactions occur between the organic oil and inorganic feldspar in the presence of water. Water promotes the oil degradation by an extra supply of H+ and OH- ions. In the oil-water-rock systems, mutual exchanges of H+ and OH- ions among minerals, water, and hydrocarbons probably result in the mutual interactions between oil degradation and mineral alteration, with water serving as a matrix for the ion exchange. In the oil-water-feldspar system, feldspar alteration does not cease in the oil zone in the presence of some water and, inversely, oil degradation can even accelerate the alterations of the aluminosilicate minerals. The mineral alterations from feldspar to boehmite, illite, and muscovite promote the oil degradation in the oil-deionized water-feldspar systems with the mutual ion exchange. Due to a possible competition between the Brønsted acid sites in the minerals and the halide anions or the direct replacement of K-feldspar by albite, the mineral alterations retard the oil degradation in the oil-NaCl water-feldspar systems. The experimental results also indicate that oil degradation via free radical cross-linking and free radical thermal cracking is extensive in anhydrous oil systems and may lead to blocking of pores and throats by the generated pyrobitumen in the oil zone of a reservoir. In contrast, in the oil-water transition zone of a reservoir, oil degradation via thermal cracking and oxidative decomposition may dominate the oil degradation and may lead to the generation of secondary pores with leaching of minerals by the generated CO2 and organic acids. This study clearly demonstrates that organic-inorganic interactions are very complex and proceed in diverse pathways in different hydrogeochemical systems. Thus, further quantitative investigations of the reaction pathways and reaction kinetics of coupled mineral alteration and oil degradation in oil-water-rock systems are merited. Meanwhile, the incorporation of such organic-inorganic reactions into geochemical models will improve the prediction of the evolution of organic and inorganic species in petroleum reservoirs.
|Full text:||(AM) Accepted Manuscript|
Available under License - Creative Commons Attribution Non-commercial No Derivatives.
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|Publisher Web site:||https://doi.org/10.1016/j.gca.2019.01.001|
|Publisher statement:||© 2018 This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/|
|Date accepted:||02 January 2019|
|Date deposited:||11 January 2019|
|Date of first online publication:||11 January 2019|
|Date first made open access:||11 January 2020|
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