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Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3

Huddart, Benjamin; Brambleby, Jamie; Lancaster, Tom; Goddard, Paul; Xiao, Fan; Blundell, Stephen J; Pratt, Francis L; Singleton, John; Macchi, Piero; Scatena, Rebecca; Barton, Alyssa; Manson, Jamie L

Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3 Thumbnail


Authors

Jamie Brambleby

Paul Goddard

Fan Xiao

Stephen J Blundell

Francis L Pratt

John Singleton

Piero Macchi

Rebecca Scatena

Alyssa Barton

Jamie L Manson



Abstract

The quasi-one-dimensional molecule-based Heisenberg antiferromagnet Cu(NO3)2(pyz)3 has an intrachain coupling J = 13.7(1) K (Image ID:c8cp07160h-t1.gif) and exhibits a state of long-range magnetic order below TN = 0.105(1) K. The ratio of interchain to intrachain coupling is estimated to be |J′/J| = 3.3 × 10−3, demonstrating a high degree of isolation for the Cu chains.

Citation

Huddart, B., Brambleby, J., Lancaster, T., Goddard, P., Xiao, F., Blundell, S. J., …Manson, J. L. (2019). Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3. Physical Chemistry Chemical Physics, 21(3), 1014-1018. https://doi.org/10.1039/c8cp07160h

Journal Article Type Article
Acceptance Date Dec 14, 2018
Online Publication Date Dec 14, 2018
Publication Date Jan 21, 2019
Deposit Date Dec 21, 2018
Publicly Available Date Dec 14, 2019
Journal Physical Chemistry Chemical Physics
Print ISSN 1463-9076
Electronic ISSN 1463-9084
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 21
Issue 3
Pages 1014-1018
DOI https://doi.org/10.1039/c8cp07160h

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