Huddart, Benjamin and Brambleby, Jamie and Lancaster, Tom and Goddard, Paul and Xiao, Fan and Blundell, Stephen J and Pratt, Francis L and Singleton, John and Macchi, Piero and Scatena, Rebecca and Barton, Alyssa and Manson, Jamie L (2019) 'Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3.', Physical chemistry chemical physics., 21 (3). pp. 1014-1018.
The quasi-one-dimensional molecule-based Heisenberg antiferromagnet Cu(NO3)2(pyz)3 has an intrachain coupling J = 13.7(1) K (Image ID:c8cp07160h-t1.gif) and exhibits a state of long-range magnetic order below TN = 0.105(1) K. The ratio of interchain to intrachain coupling is estimated to be |J′/J| = 3.3 × 10−3, demonstrating a high degree of isolation for the Cu chains.
|Full text:||(AM) Accepted Manuscript|
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|Publisher Web site:||https://doi.org/10.1039/C8CP07160H|
|Date accepted:||14 December 2018|
|Date deposited:||01 February 2019|
|Date of first online publication:||14 December 2018|
|Date first made open access:||14 December 2019|
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