Huddart, Benjamin and Brambleby, Jamie and Lancaster, Tom and Goddard, Paul and Xiao, Fan and Blundell, Stephen J and Pratt, Francis L and Singleton, John and Macchi, Piero and Scatena, Rebecca and Barton, Alyssa and Manson, Jamie L (2019) 'Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3.', Physical chemistry chemical physics., 21 (3). pp. 1014-1018.
Abstract
The quasi-one-dimensional molecule-based Heisenberg antiferromagnet Cu(NO3)2(pyz)3 has an intrachain coupling J = 13.7(1) K (Image ID:c8cp07160h-t1.gif) and exhibits a state of long-range magnetic order below TN = 0.105(1) K. The ratio of interchain to intrachain coupling is estimated to be |J′/J| = 3.3 × 10−3, demonstrating a high degree of isolation for the Cu chains.
| Item Type: | Article |
|---|---|
| Full text: | (AM) Accepted Manuscript Download PDF (5793Kb) |
| Status: | Peer-reviewed |
| Publisher Web site: | https://doi.org/10.1039/C8CP07160H |
| Date accepted: | 14 December 2018 |
| Date deposited: | 01 February 2019 |
| Date of first online publication: | 14 December 2018 |
| Date first made open access: | 14 December 2019 |
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