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Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3.

Huddart, Benjamin and Brambleby, Jamie and Lancaster, Tom and Goddard, Paul and Xiao, Fan and Blundell, Stephen J and Pratt, Francis L and Singleton, John and Macchi, Piero and Scatena, Rebecca and Barton, Alyssa and Manson, Jamie L (2019) 'Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3.', Physical chemistry chemical physics., 21 (3). pp. 1014-1018.

Abstract

The quasi-one-dimensional molecule-based Heisenberg antiferromagnet Cu(NO3)2(pyz)3 has an intrachain coupling J = 13.7(1) K (Image ID:c8cp07160h-t1.gif) and exhibits a state of long-range magnetic order below TN = 0.105(1) K. The ratio of interchain to intrachain coupling is estimated to be |J′/J| = 3.3 × 10−3, demonstrating a high degree of isolation for the Cu chains.

Item Type:Article
Full text:(AM) Accepted Manuscript
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Status:Peer-reviewed
Publisher Web site:https://doi.org/10.1039/C8CP07160H
Date accepted:14 December 2018
Date deposited:01 February 2019
Date of first online publication:14 December 2018
Date first made open access:14 December 2019

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