A solid-supported arylboronic acid catalyst for direct amidation

Du, Yihao; Barber, Thomas; Lim, Sol Ee; Rzepa, Henry S.; Baxendale, Ian R.; Whiting, Andrew

doi:10.1039/c8cc09913h

A solid-supported arylboronic acid catalyst for direct amidation

Du, Yihao; Barber, Thomas; Lim, Sol Ee; Rzepa, Henry S.; Baxendale, Ian R.; Whiting, Andrew

Authors

Yihao Du

Thomas Barber

Sol Ee Lim

Henry S. Rzepa

Professor Ian Baxendale i.r.baxendale@durham.ac.uk
Professor

Professor Andrew Whiting andy.whiting@durham.ac.uk
Emeritus Professor

Abstract

An efficient heterogeneous amidation catalyst has been prepared by co-polymerisation of styrene, DVB with 4-styreneboronic acid, which shows wide substrate applicability and higher reactivity than the equivalent homogeneous phenylboronic acid, suggesting potential cooperative catalytic effects. The catalyst can be easily recovered and reused; suitable for use in packed bed flow reactors.

Citation

Du, Y., Barber, T., Lim, S. E., Rzepa, H. S., Baxendale, I. R., & Whiting, A. (2019). A solid-supported arylboronic acid catalyst for direct amidation. Chemical Communications, 55(20), 2916-2919. https://doi.org/10.1039/c8cc09913h

Journal Article Type	Article
Acceptance Date	Feb 13, 2019
Online Publication Date	Feb 13, 2019
Publication Date	Mar 11, 2019
Deposit Date	Feb 20, 2019
Publicly Available Date	Feb 13, 2020
Journal	Chemical Communications
Print ISSN	1359-7345
Electronic ISSN	1364-548X
Publisher	Royal Society of Chemistry
Peer Reviewed	Peer Reviewed
Volume	55
Issue	20
Pages	2916-2919
DOI	https://doi.org/10.1039/c8cc09913h