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C-H activation/metalation approaches for the synthesis of indolizine derivatives.

Clososki, Giuliano Cesar and Steel, Patrick G. and Bertallo, Camila Rodrigues de Souza and Arroio, Thaís Rodrigues Arroio Rodrigues and Vessecchi, Ricardo and Toledo, Monica F. Z. J. and Sadler, Scott (2019) 'C-H activation/metalation approaches for the synthesis of indolizine derivatives.', European journal of organic chemistry., 31-32 . pp. 5205-5213.

Abstract

The C‐H borylation of indolizines has not previously been reported and in this communication, we describe our preliminary efforts to apply this chemistry to this scaffold and contrast this approach to directed metalation. Through these methodologies were possible obtain a library of substituted indolizines functionalized in both pyridinic and pyrrole ring.

Item Type:Article
Full text:(AM) Accepted Manuscript
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Status:Peer-reviewed
Publisher Web site:https://doi.org/10.1002/ejoc.201900608
Publisher statement:This is the accepted version of the following article: Clososki, Giuliano Cesar, Steel, Patrick G., Bertallo, Camila Rodrigues de Souza, Arroio, Thaís Rodrigues Arroio Rodrigues, Vessecchi, Ricardo, Toledo, Monica F. Z. J. & Sadler, Scott (2019). C-H activation/metalation approaches for the synthesis of indolizine derivatives. European Journal of Organic Chemistry 31-32: 5205-5213 which has been published in final form at https://doi.org/10.1002/ejoc.201900608. This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.
Date accepted:05 June 2019
Date deposited:06 June 2019
Date of first online publication:September 2019
Date first made open access:25 June 2020

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