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Discrepancy between bulk-rock and zircon Hf isotopes accompanying Nd-Hf isotope decoupling.

Huang, Hui and Niu, Yaoling and Teng, Fang-Zhen and Wang, Shui-Jiong (2019) 'Discrepancy between bulk-rock and zircon Hf isotopes accompanying Nd-Hf isotope decoupling.', Geochimica et Cosmochimica Acta, 259 . pp. 17-36.


Zircon is an important accessory mineral for studying the crust-mantle interaction and crustal growth through time because zircon crystals not only allow precise dating but also record initial Hf isotope ratios of the host magmas. Our study on a suite of gabbronorite, mafic diorite cumulates, diorite and granite from the Kekeli Batholith in the North Qilian Orogenic Belt, northern Tibetan Plateau, shows (1) a significant Hf isotope discrepancy between zircons and their bulk rocks; and (2) bulk-rock Nd-Hf isotopic decoupling. These observations thus demonstrate that zircons do not always capture the full history of magmatic system. The significant positive correlation between bulk-rock Hf isotope ratios and TiO2 content (R2=0.94) indicates that Ti-rich minerals (e.g., ilmenite, amphibole) are likely important Hf hosts. The early-formed Ti-rich minerals possibly record different Hf isotopes from those of zircons crystallized subsequently, thus causing discrepancy between zircons and bulk-rocks and leading to bulk-rock Nd-Hf isotope decoupling. Correlations between bulk-rock TiO2 content, Mg isotopes and Hf isotopes indicate a mixing process, with granite and gabbronorite representing two compositional endmembers. Because Ti minerals have higher crystallization temperatures than zircons, when the mixing melts have contrasting isotopes (or from heterogeneous sources/ have a strong crustal contamination), the bulk-rock and zircon Hf isotope discrepancies reflect mineral crystallization sequence during mafic and felsic magma mixing. It is thus imperative to consider early formed minerals such as Ti-rich minerals and the bulk rock composition, not just zircons, when using Hf isotopes to track melt evolution and precisely constrain mantle contribution to granitoid petrogenesis.

Item Type:Article
Full text:(AM) Accepted Manuscript
Available under License - Creative Commons Attribution Non-commercial No Derivatives.
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Publisher statement:© 2019 This manuscript version is made available under the CC-BY-NC-ND 4.0 license
Date accepted:24 May 2019
Date deposited:11 June 2019
Date of first online publication:11 June 2019
Date first made open access:11 June 2020

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