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Spectroscopic characterisation of radical polyinterhalogen molecules.

Gregory, Joe and Verlet, Jan R. R. and Bull, James N. (2020) 'Spectroscopic characterisation of radical polyinterhalogen molecules.', Physical chemistry chemical physics., 22 (16). pp. 8284-8288.


Spectroscopic characterisations of the radical polyinterhalogen molecules IF2 and I2F are reported using anion photoelectron spectroscopy. The corresponding parent anions, IF2− and I2F−, are common products formed in hard Ar–CF3I plasmas and are relevant in the semiconductor manufacture industry. The I2F− species, which is present as the [I–I–F]− isomer, is a “non-classical” polyinterhalogen.

Item Type:Article
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Date accepted:03 April 2020
Date deposited:14 May 2020
Date of first online publication:03 April 2020
Date first made open access:03 April 2021

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