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Nitrogen mass fraction and stable isotope ratios for fourteen geological reference materials: evaluating the applicability of elemental analyser versus sealed tube combustion methods.

Boocock, Toby J. and Mikhail, Sami and Prytulak, Julie and Di Rocco, Tommaso and Stüeken, Eva E. (2020) 'Nitrogen mass fraction and stable isotope ratios for fourteen geological reference materials: evaluating the applicability of elemental analyser versus sealed tube combustion methods.', Geostandards and geoanalytical research., 44 (3). pp. 537-551.

Abstract

Thirteen commercially available silicate reference materials (RM) and one in‐house reference material, eleven of which have no previously published values, were analysed for nitrogen mass fraction and isotopic ratios with an Elemental Analyser (EA), and a Sealed Tube Combustion line, coupled to a continuous flow isotope ratio mass spectrometer (IRMS). These materials ranged from < 10 μg g−1 to 1% m /m nitrogen mass fractions and δ15N of −0.5 to +19.8‰. Existing nitrogen RM BHVO‐2, MS#5 and SGR‐1b were used to assess the accuracy of the data from the sealed tube combustion line, which was found to be in good agreement with existing published values. In contrast, the EA‐IRMS failed to fully liberate nitrogen from all silicate rocks and minerals (achieving a mean of 44 ± 10% nitrogen yield) resulting in kinetic fractionation of isotope values by −1.4‰ on average. Therefore, sealed tube combustion is better suited for analyses of silicate‐bound nitrogen. The EA worked reliably for organic samples, but care should be taken when using the EA for silicate nitrogen research. Moving forward, it is recommended that BHVO‐2, Biotite‐Fe, FK‐N and UB‐N be used as quality control materials as they appear to be most reproducible in terms of nitrogen mass fraction (relative error < 10%, 1s ), and isotopic composition (< 0.6‰, 1s ).

Item Type:Article
Full text:(VoR) Version of Record
Available under License - Creative Commons Attribution.
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Full text:(VoR) Version of Record
Available under License - Creative Commons Attribution.
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Status:Peer-reviewed
Publisher Web site:https://doi.org/10.1111/ggr.12345
Publisher statement:© 2020 The Authors. Geostandards and Geoanalytical Research published by John Wiley & Sons Ltd on behalf of the International Association of Geoanalysts. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
Date accepted:19 May 2020
Date deposited:29 July 2020
Date of first online publication:17 July 2020
Date first made open access:29 July 2020

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