Aleksandra Nyga
Electrochemical and Spectroelectrochemical Comparative Study of Macrocyclic Thermally Activated Delayed Fluorescent Compounds: Molecular Charge Stability vs OLED EQE Roll‐Off
Nyga, Aleksandra; Izumi, Saika; Higginbotham, Heather F.; Stachelek, Patrycja; Pluczyk, Sandra; de Silva, Piotr; Minakata, Satoshi; Takeda, Youhei; Data, Przemyslaw
Authors
Saika Izumi
Heather F. Higginbotham
Dr Patrycja Brook patrycja.stachelek@durham.ac.uk
Royal Society University Research Fellow
Sandra Pluczyk
Piotr de Silva
Satoshi Minakata
Youhei Takeda
Przemyslaw Data
Abstract
In this work, we present how a small change in molecular structure can affect the electrochemical stability of organic compounds. A new electron donor–acceptor–donor–acceptor (D–A–D–A) macrocyclic π‐conjugated compound ( t BuMC ) comprising of dibenzophenazine as As and N,N‐ bis( t ‐butylphenyl) ‐p ‐phenylenediamines as Ds has been synthesized. The photophysical investigation uncovered that t BuMC showed thermally activated delayed fluorescence and that the organic light‐emitting diodes (OLEDs) fabricated with t BuMC as the emitter achieved high external quantum efficiency (EQEs) of ca. 10%. However, the OLED with t BuMC showed a slightly lower EQE than that of the OLED with MC (11.6%) and showed greater EQE roll‐off. Comparative studies on electrochemical properties of t BuMC , MC , and a linear analogue ( Linear ) revealed the introduction of t ‐Bu groups in the D–A–D–A scaffold causes a significant change in redox behaviour. Full electrochemical and spectroelectrochemical studies gave clues to understand how the steric hindering group is affecting the charge distribution in the new molecules which results in a significant difference in the OLED roll‐off. The electrochemical investigations together with UV‐Vis‐NIR and EPR analyses supported by quantum chemical theoretical calculations were performed, which provided us insights on the effect of structural modification on the redox properties of the D–A–D–A scaffold.
Citation
Nyga, A., Izumi, S., Higginbotham, H. F., Stachelek, P., Pluczyk, S., de Silva, P., …Data, P. (2020). Electrochemical and Spectroelectrochemical Comparative Study of Macrocyclic Thermally Activated Delayed Fluorescent Compounds: Molecular Charge Stability vs OLED EQE Roll‐Off. Asian Journal of Organic Chemistry, 9(12), 2153-2161. https://doi.org/10.1002/ajoc.202000475
Journal Article Type | Article |
---|---|
Acceptance Date | Oct 13, 2020 |
Online Publication Date | Nov 6, 2020 |
Publication Date | Dec 11, 2020 |
Deposit Date | Oct 15, 2020 |
Publicly Available Date | Nov 6, 2021 |
Journal | Asian Journal of Organic Chemistry |
Print ISSN | 2193-5807 |
Electronic ISSN | 2193-5815 |
Publisher | Wiley |
Peer Reviewed | Peer Reviewed |
Volume | 9 |
Issue | 12 |
Pages | 2153-2161 |
DOI | https://doi.org/10.1002/ajoc.202000475 |
Public URL | https://durham-repository.worktribe.com/output/1289941 |
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Copyright Statement
This is the peer reviewed version of the following article: Nyga, Aleksandra, Izumi, Saika, Higginbotham, Heather F., Stachelek, Patrycja, Pluczyk, Sandra, de Silva, Piotr, Minakata, Satoshi, Takeda, Youhei & Data, Przemyslaw (2020). Electrochemical and Spectroelectrochemical Comparative Study of Macrocyclic Thermally Activated Delayed Fluorescent Compounds: Molecular Charge Stability vs OLED EQE Roll‐Off. Asian Journal of Organic Chemistry 9(12): 2153-2161., which has been published in final form at https://doi.org/10.1002/ajoc.202000475. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
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