Peter Byrne
Guest inclusion by Borromean weave coordination networks
Byrne, Peter; Lloyd, Gareth O.; Steed, Jonathan W.
Abstract
Reaction of N,Nʺ-ethylene-1,2-diylbis(3-pyridin-3-ylurea) (L) with AgNO3 in a variety of solvents gives a total of five 2-D Borromean weave coordination polymer networks that adopt three structural types depending on the interactions to the solvent pocket. The Borromean network is of formula [Ag2(L)3](NO3)2 ·solvent where the solvent is either a cluster of water molecules, mixtures of water and acetonitrile, water and methanol or chloroform and methanol. The Borromean structure is a thermodynamic sink and under fast crystallization conditions an alternative 2 + 2 metallomacrocycle forms that can result in metallogel formation. The metallogel structure transforms into the crystalline Borromean network over time.
Citation
Byrne, P., Lloyd, G. O., & Steed, J. W. (2021). Guest inclusion by Borromean weave coordination networks. Journal of Coordination Chemistry, 74(1-3), 152-161. https://doi.org/10.1080/00958972.2021.1875132
Journal Article Type | Article |
---|---|
Acceptance Date | Jan 4, 2021 |
Online Publication Date | Jan 21, 2021 |
Publication Date | 2021 |
Deposit Date | Feb 12, 2021 |
Publicly Available Date | Mar 29, 2024 |
Journal | Journal of Coordination Chemistry |
Print ISSN | 0095-8972 |
Electronic ISSN | 1029-0389 |
Publisher | Taylor and Francis Group |
Peer Reviewed | Peer Reviewed |
Volume | 74 |
Issue | 1-3 |
Pages | 152-161 |
DOI | https://doi.org/10.1080/00958972.2021.1875132 |
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Copyright Statement
2021 The Author(s). Published by Informa UK Limited, trading as Taylor & Francis Group.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/
by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited
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