S. Dastgir
A stable crystalline imino-N-heterocyclic carbene ligand and its corresponding palladium(II) and rhodium(I) complexes
Dastgir, S.; Coleman, K.S.; Cowley, A.R.; Green, M.L.H.
Abstract
The crystalline heteroditopic, acyclic, and nonenolizable imino-N-heterocyclic carbene chelating ligand 1-tert-butyl-3-(1-phenyliminophenylmethylene)imidazol-2-ylidene (designated as C boolean AND imine) has been isolated and structurally characterized. The metal complexes [Pd(C boolean AND imine)Cl-2], [Pd(allyl)(C boolean AND imine)]-PF6, [Rh(COD)(C boolean AND imine)]PF6, and [Rh(CO)(C boolean AND imine)(2)]Cl have been prepared either by Ag transfer or by reaction with the free carbene. The palladiumt(II) complexes have been tested for catalytic application in Suzuki type C-C cross-coupling reactions of aryl bromides and the rhodium(l) complexes for the catalytic hydroformylation of 1-octene. The metal complexes [Pd(C boolean AND imine)Cl-2], [Pd(allyl)(C boolean AND imine)]PF6, and [Rh(CO)(C boolean AND imine)(2)]Cl have been structurally characterized by single-crystal X-ray diffraction.
Citation
Dastgir, S., Coleman, K., Cowley, A., & Green, M. (2006). A stable crystalline imino-N-heterocyclic carbene ligand and its corresponding palladium(II) and rhodium(I) complexes. Organometallics, 25(1), 300-306. https://doi.org/10.1021/om050775m
Journal Article Type | Article |
---|---|
Publication Date | Jan 1, 2006 |
Deposit Date | Sep 21, 2007 |
Journal | Organometallics |
Print ISSN | 0276-7333 |
Electronic ISSN | 1520-6041 |
Publisher | American Chemical Society |
Peer Reviewed | Peer Reviewed |
Volume | 25 |
Issue | 1 |
Pages | 300-306 |
DOI | https://doi.org/10.1021/om050775m |
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