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Hosomi-Sakurai reactions of silacyclohexenes.

Hughes, N. J. and Pullin, R. D. C. and Sanganee, M. J. and Sellars, J. D. and Steel, P. G. and Turner, M. J. (2007) 'Hosomi-Sakurai reactions of silacyclohexenes.', Organic & biomolecular chemistry., 5 (17). pp. 2841-2848.


Silacyclic allyl silanes, derived from silene–diene Diels–Alder reactions, combine with acetals in the presence of Lewis acids to afford, following oxidation of the intermediate fluorosilane, either butane-1,4-diols or tetrahydronaphthalenes containing four contiguous chiral centres with moderate to good diastereoselectivity.

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Date of first online publication:July 2007
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